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When you create a value list, providing an Other choice as a catchall is often helpful. In a value list to be used with a Shipping Method field, for example, you might list choices for Federal Express, UPS, and USPS. Because your company occasionally uses other carriers, you can add an Other choice to the value list so that they, too, can be recorded. In performing an ascending or descending sort on such a field, FileMaker Pro arranges the records in which the Other choice was selected according to the actual contents of the field (Yellow Cab, Jimmy s Messenger Service, and so on). That is, it doesn t group all the records together as though they all contained the same value (that is, Other). On the other hand, when FileMaker Pro performs a custom sort based on a value list (rather than a simple ascending or descending sort), all Other choices are grouped together at the end of the database, followed only by records in which nothing at all was chosen or entered for the field. (The procedure for adding an Other choice to a value list is described in 5.)

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7.4 ELEMENTAL BIOGEOCHEMICAL CYCLES: CONCEPTS AND PHYSIOLOGICAL PROCESSES Complex mixtures of elements are cycled through food chains in nature

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The first results of anionic polymerization (the polymerization of 1,3-butadiene and isoprene induced by sodium and potassium) appeared in the literature in the early twentieth century.168,169 It was not until the pioneering work of Ziegler 170 and Szwarc,171 however, that the real nature of the reaction was understood. Styrene derivatives and conjugated dienes are the most suitable unsaturated hydrocarbons for anionic polymerization. They are sufficiently electrophilic toward carbanionic centers and able to form stable carbanions on initiation. Simple alkenes (ethylene, propylene) do not undergo anionic polymerization and form only oligomers. Initiation is achieved by nucleophilic addition of organometallic compounds or via electron transfer reactions. Hydrocarbons (cylohexane, benzene) and ethers (diethyl ether, THF) are usually applied as the solvent in anionic polymerizations. A unique characteristic of anionic polymerization is the "living" nature of the process recognized and pioneered by Szwarc. 120,128,129,172 Living polymerization can be achieved when the rate of initiation is very fast and much faster than the rate of propagation. In living polymers the active centers are highly stable and highly reactive, and, in the absence of impurities, no spontaneous transfer or termination occurs. Under such conditions all macromolecules grow proportionally and propagation continues until an equilibrium with the monomer is established. Suitable reagents may be used to annihilate the reactive end known as "killing." Addition of water or any proton donor, for example, converts the active chain ends, resulting in a dead polymer. Living anionic polymerization allows the synthesis of homodisperse polymers (i.e., polymers with very narrow molecular weight distribution) and block copolymers unaccessible by other techniques (see Section 13.2.6). Following the interest and extensive studies of living polymers spurred by the work of Szwarc, anionic polymerization probably became the most studied and best understood of all polymerization methods.

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Table 3-10 (continued)

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2. Next, click the pin button next to the tab. This toggles the state of the button and pins the current script. It then opens a second tab to the left of the first. Figure 2-12 shows this. The new tab will open to the pinned script. Figure 2-12: After you have pinned a script, the second tab appears.

The path length is more than an order of magnitude larger than the grid gap, consistent with our assumption. The very long path length compared with grid hole spacing means that the computational space in ion optics codes is very long (several centimeters), and so the computer codes must allow for the axial zone sizes to increase downstream of the grids.

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Pr{Y y, Xt k, Xt 1 } at (k)q( yt 1 = )P( =k)bt 1 ( ), we have Pr{Y y}

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